The largest town in the Loire Valley after Tours, Orléans is a good base to begin exploring the region. Inseparably bound with the history of Joan of Arc, the city owes its survival to the 17-year-old "Maid of Orléans," who helped lead the French to victory against the English when Orléans was besieged in 1429. A small museum in a restored 15th-century house, the Maison de Jeanne-d'Arc is devoted to Joan of Arc, who is now recognized as a saint by the Catholic Church.

Another landmark associated with Joan of Arc, where she spent time in silent prayer, is the 13th-century Cathédrale Sainte-Croix. The cathedral's monumental exterior features twin towers (81 meters high), five doorways, and elaborate Baroque decoration. The sheer size of the interior leaves a lasting impression, while colorful stained-glass windows allow visitors to marvel at the history of Joan of Arc. 

For a further immersion into the city's culture, tourists can peruse the art collection at the Musée des Beaux-Arts, which displays around 700 artworks (paintings, sculptures and decorative objects) from the 15th to the 20th century, such as pieces by Correggio, Tintoretto, Delacroix, Gauguin, and Picasso.

About 27 kilometers away from Orléans is the Château de Meung-sur-Loire, one of the oldest castles in the Loire Valley. Set in expansive parklands, the château reveals the evolution of French architecture with its variety of architectural details, from 12th-century towers to the 18th-century facade. The castle also played a strategic role for Joan of Arc in 1429 at a crucial moment during the Hundred Years' War.